You probably have heard that the most popular HFC
refrigerants being widely used today are global warming gasses. In fact, some popular
HFC refrigerants have higher GWPs than the CFCs and HCFCs they replaced. A
refrigerant’s Global warming potential (GWP) compares it to CO
2, the
global warming gas produced by burning hydrocarbons. A GWP of 1 indicates that
a gas has the same effect on global warming as CO
2. The retired
popular air conditioning refrigerant, HCFC 22, has a GWP of 1760. HFC 410A that is now widely used in air
conditioning applications has a GWP of 1924. It is actually worse! Meanwhile
HFC 404A, popular in refrigeration applications, has a GWP of 3943. HFC 134a is
popular in domestic refrigerators, commercial refrigeration, and car air
conditioning has a GWP of 1300. These high GWP numbers have made HFC
refrigerants the target of regulatory efforts to limit their use and replace
them with more environmentally friendly refrigerants. Europe has moved
aggressively, passing their F-Gas regulations. The ultimate objective of the
F-Gas Regulations is to cut the availability of HFCs by 79% between 2015 and
2030. There will also be a servicing ban on HFCs with a GWP >2500 for
certain sectors.
Here is a link to a quick overview of the F-Gas regulations byMitsubishi.
While the US has not moved nearly as aggressively, there
have been attempts by the EPA to regulate refrigerants based on their GWP. Worldwide
regulatory restrictions on current HFC refrigerants has spurred development of
lower GWP refrigerants. Manufacturers in the HVACR industry have been actively
developing lower GWP alternative refrigerants.
HYDROCARBONS
Propane (R290), Isobutane (R600a), and R441A all have very
low GWPs of (3, 3,0). They are all non-ozone depleting and non-toxic. Their
limitation is their flammability – they are all highly flammable. In the US
they are approved only for systems with a charge of 150 grams (5 ounces) or
less. In Europe hydrocarbon refrigerants have been used in refrigerators and
freezers for years. These refrigerants are now common in residential refrigerator
and small commercial refrigeration units in the US. While highly flammable
refrigerants are likely to remain a factor in small commercial refrigeration
systems, it is unlikely that these refrigerants will be used in larger systems
in the US due to our aversion for being sued and the large number of lawyers in
the US.
CO2 R744
It is interesting that the main global warming culprit, CO
2,
is also a refrigerant with a very low GWP of 1. It does not deplete the ozone,
it is non-toxic, non-flammable, and cheap. What’s not to like? Unfortunately,
CO
2 has a critical temperature of 88°F. It cannot condense above
88°F. This means that CO
2 systems are not “normal” systems. CO
2
systems must either be transcritical or cascade systems. Transcritical systems operate
at very high pressures of 1200 – 1500 psig on the high side. Cascade systems
use the evaporator of one system to cool the condenser of another system.
Either way, CO
2 systems are more complicated and expensive than traditional
system. One place that CO
2 has taken root is in large scale
commercial refrigeration rack systems. Complexity in large rack refrigeration systems
is normal and the extra cost of the transcritcial components is offset by the
savings in refrigerant cost. However, in smaller scale systems the cost of a CO
2
system is prohibitive. For a quick explanation of a transcritical system check
out
https://www.achrnews.com/articles/94092-co2-as-refrigerant-the-transcritical-cycle
AMMONIA R717
Ammonia refrigeration has been around since the earliest
days of refrigeration. Ammonia has always been used in large scale food
commercial refrigeration and freezing for food processing because of its
efficiency and low cost. Unfortunately, ammonia (R-717) has many application
challenges. It is toxic, somewhat flammable, and cannot be used with some
metals, such as brass or copper. It will continue to be a mainstay of
commercial food processing, but I doubt you will see it expand into other
market segments.
LOWER GWP HFCs
There are some HFC refrigerants that have a GWP in the
hundreds instead of the thousands. While these refrigerants are probably not
long-term solutions, they can provide a way to drastically reduce the GWP
footprint of a system without a drastic change in technology or design.
R 32
HFC R-32 has been adopted by many manufacturers in air
conditioning systems sold outside of the United States. R-32 is an HFC with a
lower GWP of 667. That is still not really low compared to CO2 (GWP 1) or
ammonia (GWP 0), but it is considerably lower than R404A, R410A, or R134a. HFC32
has the advantage of being a relatively “normal” refrigerant, making designing
systems to use it less challenging than say, CO
2. However, R-32 is
flammable. While not as flammable as propane, it does burn. That precludes its
use in most applications in the US, at least right now. The building and safety
codes in the US do not allow a flammable refrigerant in systems where the air
in the building flows directly over the evaporator. These codes make no
distinction between A2L and A3 refrigerants. To them, flammable is flammable. Manufacturers and code officials in the US are
working to determine what new requirements an A2L refrigerant system should
have to make it safe for use. The one place you will find R32 in the US is in
window air conditioners. The EPA allows use of R32 in limited quantities in
window units.
Here is a link for more information on R32.
R466A (Solstice N41)
Honeywell has developed an A1 rated, non-flammable HFC based
refrigerant with a GWP of 733. Like R-32, R-466A provides a refrigerant with a
much lower GWP than HFC refrigerants currently in use, but not really low. Its
big advantage over R32 is that it is non-flammable. R466A achieves this by
using a mix of 49% R32, 11.5% R125, and 39.5% R1311. R32 and R125 are the two
components found in R410A. R1311 has been previously used as a fire suppressant.
This blend performs similarly to R410A, making adoption relatively easy.
Here is a link to more information on R466A.
HFOs
Hydrofluoroolefins (HFOs) are a special type of HFC. They
have at least one carbon double bond, making them less chemically stable than a
“normal” HFC which has all single bonds. Because they are less chemically
stable, they do not persist in the atmosphere for long, and this reduces their
global warming potential. For example, HFO1233zd has a GWP of 0. HFO1233zd is a
low pressure refrigerant for chiller applications. It has an A1 safety rating
and does not deplete the ozone. HFO1234yf has a GWP less than 1. It has an A2L
safety rating – meaning that it is somewhat flammable. HFO1234yf is used in
auto air conditioning systems. It has been what most auto manufacturers now use
instead of HFC134a. Here is a link to more information on HFOs.
Lower GWP refrigerants are the future of HVACR. Some old and
some new. Understanding how to safely work with these lower GWP refrigerants
will be an important part of all technician’s knowledge set going forward.